A vibronic analysis of the 2Eg → 4A2g transition in solid Cs2MnF6
✍ Scribed by C.D Flint
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 585 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-2852
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CalcuIations of the vibronic bandshape of the 'E o -+ 4Azg transition in octahedral 3d3 complexes are presented. The vibrcmic intensity is expressed in terms of lore&an functions centered around the fundamental odd vibrations of the complex in respect to the 0-O line and weighted by coupling coeffic
Dispersed fluorescence spectra in the spectral range 475-575 nm and fluorescence excitation spectra in the range 2 2 + • 13 34 • • • 410-480 nm were recorded for the A H -X II system of CS 2 and as C-and S-motoplc speoes Based on a u g • • 13 34 ..... 2 comparison of the relative extents of C-and S-
A nophonon transitIon has been observed III CszNaSmCle at 6355 cm -l This translrlon IS assigned, m octahedral symmetry, as E';(6Hs,2) -t E;(6F, n) and 1s proposed to be of pure electric quadrupole orlgm A comparison between the experunental and calculated mtenslty and the orlentatlondependent inten