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Observation of a possible pure electric quadrupole transition in solid Cs2NaSmCl6

✍ Scribed by Robert W. Schwartz; Asok K. Banerjee

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 294 KB
Volume: 79
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85279-7

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✦ Synopsis

A nophonon transitIon has been observed III CszNaSmCle at 6355 cm -l This translrlon IS assigned, m octahedral symmetry, as E';(6Hs,2) -t E;(6F, n) and 1s proposed to be of pure electric quadrupole orlgm A comparison between the experunental and calculated mtenslty and the orlentatlondependent intensity of an associated v,broruc transition lend support to this assgflment We have observed a transItIon m a smgie crystal of the cubic flexacflloroelpasohte C!s2NaSmCf6

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