Calculation of the rate constant for the reaction of atomic hydrogen with molecular oxygen to form the free radical HO2
โ Scribed by Blint, Richard J.
- Book ID
- 120274448
- Publisher
- American Institute of Physics
- Year
- 1980
- Tongue
- English
- Weight
- 698 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.440182
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Reactions of HCCCO and NCCO radicals with O 2 have been studied by a combination of pulsed laser photolysis and photoionization mass spectrometry. HCCCO was produced by 193-nm photolysis of methylpropiolate or 3-butyn-2-one, and NCCO was formed by 193-nm photolysis of acetylcyanide. The rate constan
## Abstract A phaseโshift method has been used to determine the rate constant for the reaction of ground state oxygen atoms with HCl over the temperature range of 330โ600 K. Oxygen atoms were generated by modulated mercury photosensitized decomposition of N~2~O, and monitored by the chemiluminescen