𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Calculation of the preexponential factor for the reaction ĊH3+C2H4

✍ Scribed by B. Yu. Ainbinder; M. V. Bazilevskii

Publisher
SP MAIK Nauka/Interperiodica
Year
1968
Tongue
English
Weight
257 KB
Volume
9
Category
Article
ISSN
0022-4766

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Radical hydrogen transfer reactions: ben
Radical hydrogen transfer reactions: benchmark calculations on the C2H4…H…C2H4 transition state
✍ John D. Watts; James A. Franz; Rodney J. Bartlett 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 337 KB

High level ab initio calculations using coupled-cluster (CC) methods have been applied to calculate the barrier height of the prototypical hydrocarbon radical hydrogen transfer reaction between C 2 H 4 and C 2 H 5. The barrier at 298 K is estimated to be 27.7-30.7 kcal mol-~. Second-order perturbati

New calculations on the ion—molecule pro
New calculations on the ion—molecule processes C2H+2 + H2 → C2H+3 + H and C2H+2 + H2 → C2H+4
✍ Sergio A. Maluendes; A.D. McLean; Eric Herbst 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 473 KB

New high-level quantum chemical calculations have been undertaken to understand the rates and mechanisms of the reactive and associative channels for the reactants C2H2(+) + H2. The reactive channel, which produces C2H3(+) + H, has been shown to be slightly endothermic, confirming earlier calculatio

The formation of (CH3)3Ċ, H2ĊC(Me)2OH an
The formation of (CH3)3Ċ, H2ĊC(Me)2OH and ĊH3 radicals in the radiolysis of aqueous t-butyl alcohol: on the solvation of t-butyl alcohol by water
✍ K.V.S. Rao; M.C.R. Symons 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 170 KB

Esppsure of aqueous glassy solutions of f-butyl alcohol to 6oCo vlays at 77°K gave ESR spectra characteristic of h!e& and H2CC(hfe)20H radicals. The results for the former were unusual in fh?t, for very dilute aqueous solutions and for solutions of 0.4 mole fraction through to the pure alcohol, all

Arrhenius parameters for the reactions C
Arrhenius parameters for the reactions CH3. + C4H10 → CH4 + C4H9. and C2H5. + C4H10 → C2H6 + C4H9.
✍ P. D. Pacey; J. H. Purnell 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB 👁 1 views

Study of n-butane pyrolysis at high temperature in a flow system allows measurement of the sum of the rate constants of the initiation reactions (2) and of the Arrhenius parameters of the reactions Established data for kl/k2 allow estimation of kl for 951'K and this, with recent thermochemical da