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Calculated ro-vibrational spectrum of 7Li+3 and 7Li2 6Li+

✍ Scribed by James R. Henderson; Steven Miller; Jonathan Tennyson

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 325 KB
Volume: 44
Category: Article
ISSN: 1386-1425
DOI: 10.1016/0584-8539(88)80171-5

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✦ Synopsis

Calculated ro-vibrational energy levels (J ~< 4) and transition intensities are presented for the two most abundant isotopomers of Li~. The calculations use the recent ab initio potential energy surface of ~EARLES et al. (Spectrochim. Acta 43A, 699 (1987); 44A~ 505 (198~;); 44A, 985 (1988))• The rotational levels of the ground state and vibrational fundamentals are given in terms of parameterised Hamiltonians due to WATSON retaining terms to fourth-order. The small splitting of the degenerate v 2 mode in the mixed isotopomer leads to strong Coriolis coupling between the v 2 and v 3 in 7Lia6Li+.

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