Pressure-induced amorphization of Li2GeO3 and Li6Ge2O7 crystals
β Scribed by Yongwei Xu; Yudong Li; Guoxiang Lan
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 344 KB
- Volume
- 52
- Category
- Article
- ISSN
- 1386-1425
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β¦ Synopsis
A high-pressure Raman scattering study reveals that crystalline Li2GeO 3 and Li6Ge207 transform into the amorphous state at 12 and 11 GPa respectively. The pressure-induced amorphizations are reversible within a certain range above the starting transition pressure and are irreversible above 20 GPa. The pressure-induced amorphization of the series of lithium germanate crystals is closely related to their composition and structure: with increasing Li20 content of these crystals the amorphization transition pressure decreases.
π SIMILAR VOLUMES
Calculated ro-vibrational energy levels (J ~< 4) and transition intensities are presented for the two most abundant isotopomers of Li~. The calculations use the recent ab initio potential energy surface of ~EARLES et al. (Spectrochim. Acta 43A, 699 (1987); 44A~ 505 (198~;); 44A, 985 (1988))β’ The rot