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Cage effect on the photolysis of chlorine in solution

✍ Scribed by K. Brady Clark; David Griller

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
445 KB
Volume
168
Category
Article
ISSN
0009-2614

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✦ Synopsis

The photodissociation quantum yield of chlorine in CC14 was determined at 308 and 337 nm using the technique of Iascrinduced photoacoustic calorimetry (PAC). The quantum yield for photodissociation was observed to be wavelength dependent (0.16 and 0.22 at 337 and 308 nm, respectively). This wavelength dependence originates in the excess energy that is delivered to the geminate radical pair.

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