CaCl2-Catalyzed Functionalization of Saturated Hydrocarbons with CO to Carboxylic Acids and Esters
โ Scribed by Mohammad Asadullah; Tsugio Kitamura; Yuzo Fujiwara
- Book ID
- 112256194
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 111 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0021-9517
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The reactions of a,b-unsaturated aldehydes such as (E)-cinnamaldehyde and 2-or 4-methoxycinnamaldehyde with trimethylsilyl cyanide in the presence of a catalytic amount of a Lewis base such as TTMPP and DBU afforded the corresponding saturated carboxylic acids after hydrolysis.
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The Conversion of Saturated Hydrocarbons into Carboxylic Acids Using Fe(CO)5-H2O2 Oxidation. -Hydrocarbons such as cyclohexane or adamantane are transformed predominantly to homologous acids such as (I) and (II) with Fe(CO)5 and H2O2 in pyridine/HOAc. -(BARTON, D. H. R.;