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Lewis base-catalyzed transformation of α,β-unsaturated aldehydes to saturated carboxylic acids, esters and amides

✍ Scribed by Hirotoshi Kawabata; Masahiko Hayashi

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
62 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

The reactions of a,b-unsaturated aldehydes such as (E)-cinnamaldehyde and 2-or 4-methoxycinnamaldehyde with trimethylsilyl cyanide in the presence of a catalytic amount of a Lewis base such as TTMPP and DBU afforded the corresponding saturated carboxylic acids after hydrolysis.

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