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C -Glycosylation Reactions of Sulfur-Substituted Glycosyl Donors: Evidence against the Role of Neighboring-Group Participation

โœ Scribed by Beaver, Matthew G.; Billings, Susan B.; Woerpel, K. A.


Book ID
120267259
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
99 KB
Volume
130
Category
Article
ISSN
0002-7863

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โœ Ying Zeng; Jun Ning; Fanzuo Kong ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 165 KB

Predominant or even pure (13)-a-linked products can be generated in glycosylation with glucosyl trichloroacetimidate donors with a C2 ester capable of neighboring group participation. Benzoylation of either the donors or acceptors gave more b-linkage, while 4,6-O-benzylidenation of the acceptor gave