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(Butadiene)tricarbonylosmium synthesis and structural comparison with the Fe- and Ru-complexes based on 1H- and 13C-NMR. Spectroscopy

✍ Scribed by Susanne Zobl-Ruh; Wolfgang Von Philipsborn

Publisher
John Wiley and Sons
Year
1980
Tongue
German
Weight
386 KB
Volume
63
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The photochemical synthesis of the title complex from 1,3‐butadiene and dodecacarbonyltriosmium is described. The ^1^H‐NMR. and H‐coupled ^13^C‐NMR. spectra are analyzed completely and the H, H‐ and C,H‐coupling constants compared with the data of the corresponding Fe‐ and Ru‐complexes. One‐bond ^13^C, ^13^C‐coupling constants are reported for a series of complexed 1,3‐dienes. All data are consistent with an increasing distortion from planarity of the C,H‐skeleton at the terminal diene C‐atoms in the sequence Fe → Ru → Os.

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