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1H and 13C NMR studies on nitrosonaphthols, and their complexation with the dioxouranium(VI) ion

✍ Scribed by Anto Vainiotalo; Jouko Vepsäläinen

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
434 KB
Volume
24
Category
Article
ISSN
0749-1581

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✦ Synopsis

The 'H and I3C NMR spectra of l-nitroso-2-naphthol and its disodium 3,ddisulphonate, 2-nitroso-l-naphthol and its sodium 4-sulphonate and the complexes of the sulphonated ligands with dioxouranium(VI) were recorded and analysed. The results show the nitrosonaphthols exist predominantly in the oxime form, and that the l-nitroso compounds have a preferred structure. The quinonoid oxygen does not take part in the complexation with dioxouranium(VI), which is effected by chelation through the oxime oxygen and nitrogen.

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