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Bridgehead Oxiranyl Sesquiterpenoids. Asymmetric Total Synthesis of (−)-Salsolene Oxide

✍ Scribed by Paquette, Leo A.; Sun, Li-Qiang; Watson, Timothy J. N.; Friedrich, Dirk; Freeman, Brett T.


Book ID
126828036
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
150 KB
Volume
119
Category
Article
ISSN
0002-7863

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Total synthesis of (+)-epolactaene was accomplished by a convergent approach utilizing the fluoride anioncatalyzed aldol-type reaction of (-)-ot-trimethylsilylangelica lactone epoxide with tetraene aldehyde as a key reaction.