Borane reduction of uracil derivatives
โ Scribed by Ghosh, Chandrakanta; Schmidt, Diane Grob; Pal, Bimal C.
- Book ID
- 115459522
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 316 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Oxime ethers of acetophenone, isopropyl methyl ketone, and tert-butyl methyl ketone were reduced to the corresponding hydroxylamine ethers of 45-94% ee with borane-oxazaborolidine 1 derived from (-)-norephedrine. A one-pot reduction of acetophenone oxime with 1 to 1-phenylethylhydroxylamine of 87% e
## Abstract For Abstract see ChemInform Abstract in Full Text.
A number of reducing reagents were assessed in the transformation of chlorophosphine boranes to secondary phosphine boranes. The efficiency of the process requires judicious matching between steric and electronic requirements of reductant and the substrate. The stereochemistry of the reduction was i