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Mild reduction of chlorophosphine boranes to secondary phosphine boranes

✍ Scribed by Hubert Lam; David J. Aldous; King Kuok (Mimi) Hii

Book ID: 104253898
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 98 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01225-5

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✦ Synopsis

A number of reducing reagents were assessed in the transformation of chlorophosphine boranes to secondary phosphine boranes. The efficiency of the process requires judicious matching between steric and electronic requirements of reductant and the substrate. The stereochemistry of the reduction was investigated by using a chiral precursor.

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