A number of reducing reagents were assessed in the transformation of chlorophosphine boranes to secondary phosphine boranes. The efficiency of the process requires judicious matching between steric and electronic requirements of reductant and the substrate. The stereochemistry of the reduction was i
✦ LIBER ✦
A straightforward synthesis of unsymmetrical secondary phosphine boranes
✍ Scribed by Petit, Christelle; Favre-Réguillon, Alain; Mignani, Gérard; Lemaire, Marc
- Book ID
- 121473202
- Publisher
- Royal Society of Chemistry
- Year
- 2010
- Tongue
- English
- Weight
- 129 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1463-9262
- DOI
- 10.1039/B920324A
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Mild reduction of chlorophosphine borane
✍
Hubert Lam; David J. Aldous; King Kuok (Mimi) Hii
📂
Article
📅
2003
🏛
Elsevier Science
🌐
French
⚖ 98 KB
Stereoselective, Oxidative One-Carbon De
✍
Nagata, Kazuto; Matsukawa, Satoru; Imamoto, Tsuneo
📂
Article
📅
2000
🏛
American Chemical Society
🌐
English
⚖ 61 KB
Hydrophosphination of α,β-unsaturated es
✍
Karine Bourumeau; Annie-Claude Gaumont; Jean-Marc Denis
📂
Article
📅
1997
🏛
Elsevier Science
🌐
French
⚖ 216 KB
The reactivity of primary phosphine-boranes RPH2'BH 3 (R = Ph and Me) towards CH2=CHCO2Me and CH2=CHP(O)(OMe)2 is discussed. Hydrophosphination is the major process. The presence of the free phosphine (0-20%) in the crude media indicates that a competitive hydroboration reaction also occurs. The P-H
ChemInform Abstract: Stereoselective, Ox
✍
Kazuto Nagata; Satoru Matsukawa; Tsuneo Imamoto
📂
Article
📅
2000
🏛
John Wiley and Sons
⚖ 29 KB
👁 1 views
ChemInform Abstract: Hydrophosphination
✍
K. BOURUMEAU; A.-C. GAUMONT; J.-M. DENIS
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 31 KB
👁 1 views
Synthesis of unsymmetrical P-stereogenic
✍
Imoto, Hiroaki; Kato, Ryosuke; Morisaki, Yasuhiro; Chujo, Yoshiki
📂
Article
📅
2012
🏛
Nature Publishing Group
🌐
English
⚖ 790 KB