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Bis(μ-N-tert-butyl-2-{N-[2-(dimethyl­amino)eth­yl]-N-methyl­amino}ethanaminato)dilithium(I)

✍ Scribed by Chrzanowski, Lars S. von ;Lutz, Martin ;Spek, Anthony L.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
190 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound [Li~2~(C~11~H~26~N~3~)~2~], is a dimer chelate complex and features a planar Li~2~N~2~ ring with an Li...Li distance of 2.449 (3) Å and a bicyclic ring system. The coordination geometry of both Li atoms is distorted tetrahedral, each Li unit being surrounded by two amide and two amine N atoms.


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N,N′-Bis[2-(dimethyl­amino)eth­yl]dithio
✍ Cui, Jian-Zhong ;Zhang, Dan ;Zhang, Hong ;Pan, Shuo-Wen ;Cheng, Peng ;Liao, Dai- 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 116 KB

In the title compound, C 10 H 22 N 4 S 2 , molecules lie across crystallographic inversion centres. Weak N-HÁ Á ÁN and N-HÁ Á ÁS hydrogen-bonding interactions are observed in the molecular structure.