Bis{μ-N-[(N,N-dimethylamino)dimethylsilyl]-2,6-dimethylanilido}lithium(I)
✍ Scribed by Ren, Guang-Ming ;Shang, Dong-Lin ;Guo, Jian-Ping
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 208 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The dimeric lithium amide, [Li~2~(C~12~H~21~N~2~Si)~2~], exhibits a four-rung ladder core of Li—N and Si—N bonds.
📜 SIMILAR VOLUMES
The structure of the title compound, [Al 2 (CH 3 ) 4 (C 10 H 12 NO) 2 ] or [Me 2 Al{-(2,6-Me 2 C 6 H 3 )NCMeO}] 2 , consists of a fourcoordinate dimeric centrosymmetric eight-membered ring Alcontaining species.
The title compound [Li~2~(C~11~H~26~N~3~)~2~], is a dimer chelate complex and features a planar Li~2~N~2~ ring with an Li...Li distance of 2.449 (3) Å and a bicyclic ring system. The coordination geometry of both Li atoms is distorted tetrahedral, each Li unit being surrounded by two amide and two a
In the title compound, C 10 H 22 N 4 S 2 , molecules lie across crystallographic inversion centres. Weak N-HÁ Á ÁN and N-HÁ Á ÁS hydrogen-bonding interactions are observed in the molecular structure.
Di-l-acetato-bis[l-2-hydroxy-N,N 0 0 0 -bis(2-oxidobenzyl)propane-1,3-diamine]bis(N,N 0 0 0 -dimethylformamide)trinickel(II) N,N 0 0 0 -dimethylformamide disolvate