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Bis(μ-N-n-propyl-N-tri­methyl­silyl­benzamidinato)­bis­[(diethyl ether-O)­lithium]

✍ Scribed by Boyd, Catherine L. ;Tyrrell, Ben R. ;Mountford, Philip


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
204 KB
Volume
58
Category
Article
ISSN
1600-5368

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✍ Lensink, Cornelis ;Gainsford, Graeme J. ;Brandsma, Menno J. R. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 162 KB

The title compound, [Ti(C 21 H 26 N 2 O 2 S)Cl 2 ], crystallizes as a centrosymmetric dimer, with an eight-membered ring derived from the monomer sub-units by the formation of two TiÐ (N,O)ÐSÐO head-to-tail sequences around a crystallographic inversion centre. The titanium atoms each have a distorte