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Bis(μ-N-(3-[3-indenyl]propyl-p-toluenesulfamido-N,O,O′)-dimethylamidodichorotitanium)

✍ Scribed by Lensink, Cornelis ;Gainsford, Graeme J. ;Brandsma, Menno J. R.

Publisher: International Union of Crystallography
Year: 2002
Tongue: English
Weight: 162 KB
Volume: 58
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536802015787

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✦ Synopsis

The title compound, [Ti(C 21 H 26 N 2 O 2 S)Cl 2 ], crystallizes as a centrosymmetric dimer, with an eight-membered ring derived from the monomer sub-units by the formation of two TiÐ (N,O)ÐSÐO head-to-tail sequences around a crystallographic inversion centre. The titanium atoms each have a distorted octahedral geometry through the nitrogen and one oxygen of the sulfonamido group [Ti1ÐO1, TiÐN1 2.280 (3), 2.091 (3) A Ê ], one oxygen from the adjacent sulfonamide [TiÐ O2 2.170 (3) A Ê ], a dimethylamido nitrogen and two chlorides.

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Bis(μ-N-(3-[3-indenyl]­propyl-p-toluene­sulf­amido-N,O,O′)-di­methyl­amido­dichorotitanium)

✦ Synopsis

Bis(μ-N-(3-[3-indenyl]propyl-p-toluenesulfamido-N,O,O′)-dimethylamidodichorotitanium)