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Bis(μ-2-{[3-(dimethylamino)propyl]iminomethyl}phenolato-κ4N,N′,O:O)bis[(acetato-κ2O,O′)cadmium(II)] monohydrate

✍ Scribed by Cai, Wen-Xuan ;Zheng, Xiao-Yong ;Su, Hong ;Feng, Yun-Long

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 506 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807052105

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✦ Synopsis

In the crystal structure of the title compound, [Cd~2~(C~12~H~17~N~2~O)~2~(C~2~H~3~O~2~)~2~]·H~2~O, the binuclear complex molecule as well as the water molecule occupy special positions on the same twofold axis. The Cd^II^ atom has a severely distorted octahedral coordination formed by two deprotonated bridging phenol O atoms, the imine and amine N atoms of the Schiff base and two O atoms of the chelating acetate group. The water H atom takes part in a hydrogen bond involving one of the acetate O atoms as an acceptor. Each water molecule forms two such bonds, thus producing isolated 1:1 complex molecule–water aggregates in the crystal structure.

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