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Bis(μ-hydroxo) bridged di-vanadium-catalyzed selective epoxidation of alkenes with H2O2

✍ Scribed by Noritaka Mizuno; Yoshinao Nakagawa; Kazuya Yamaguchi


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
177 KB
Volume
251
Category
Article
ISSN
1381-1169

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H2O2-based epoxidation of bridged cyclic
✍ Feixue Gao; Toshihiro Yamase; Hideo Suzuki 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 275 KB

The H 2 O 2 -based epoxidation of bridged cyclic alkenes in a monophasic system containing low concentrations (1) (with two 2 -peroxotitanium sites in the anion) has been studied in search of the catalytically active species involved. 31 P NMR spectra of 1, measured under a variety of conditions, r