[{W(O)(O2)2(H2O)}2(μ-O)]2–-Catalyzed Epoxidation of Allylic Alcohols in Water with High Selectivity and Utilization of Hydrogen Peroxide
✍ Scribed by Keigo Kamata; Kazuya Yamaguchi; Shiro Hikichi; Noritaka Mizuno
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 74 KB
- Volume
- 345
- Category
- Article
- ISSN
- 1615-4150
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## A selected ion flow tube (SIFT) experimental investigation has been carried out of the reactions of H 3 O , NO and O 2 with NO, NO 2 , N 2 O and HNO 2 , in order to obtain the essential kinetic data for the analyses of these compounds in air using selected ion flow tube mass spectrometry (SIFT-M
G (m-OH) 2 ] 3À has been used as a catalyst in the chemoselective oxidation of various kinds of electron-deficient alkenes, with acetate, ether, carbonyl, and chloro groups at the allylic positions, to give the corresponding epoxides in high yields with only an equimolar amount of H 2 O 2 . Even acr