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Bis[μ-3,3′-dimethyl-3,3′-methyl­enebis(2,3-dihydro-1H-imidazole)]disilver(I)(Ag—Ag) dichloride hemihydrate

✍ Scribed by Wang, Da-Qi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
133 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Ag~2~(C~9~H~12~N~4~)~2~]Cl~2~·0.5H~2~O, each Ag^I^ atom is coordinated by two C atoms of two heterocyclic carbene ligands, displaying a nearly linear geometry. The Ag—Ag separation is quite long, indicating a very weak metal–metal interaction.

📜 SIMILAR VOLUMES

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The title compound, [Ag~2~(C~12~H~9~N~3~)~2~](NO~3~)~2~, was prepared under hydrothermal conditions. The structure consists of binuclear complex cations and nitrate anions. The two Ag^I^ atoms, each in a geometry somewhat distorted from linear, are bridged by two 2-(3-pyridyl)benzimidazole ligands _

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The asymmetric unit of the title complex, [Ag 6 (C 8 H 6 N 3 ) 6 ], contains one half-molecule; the molecule is centrosymmetric. The Ag atoms form two nearly equilateral triangles, with AgÁ Á ÁAg distances of 3.725 (3), 3.741 (3) and 3.843 (2) A ˚. ## Related literature For general background, se

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