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[μ-1,1′-Bis(2,4,6-trimethyl­benz­yl)-3,3′-(2,3,5,6-tetra­methyl-p-phenyl­enedibenzimidazole)-2,2′-diyl­idene]di-μ-bromo-disilver(I)

✍ Scribed by Koşar, Başak ;Türkmen, Hayati ;Çetinkaya, Bekir ;Büyükgüngör, Orhan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
263 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

0 -Bis(2,4,6-trimethylbenzyl)-3,3 0 0 0 -(2,3,5,6-tetramethyl-p-phenylenedibenzimidazole)-2,2 0 0 0 -diylidene]di-l-bromo-disilver(I) Bas ¸ak Kos ¸ar, a Hayati Tu ¨rkmen, b Bekir C ¸etinkaya b and Orhan Bu ¨yu ¨kgu ¨ngo ¨ra *

📜 SIMILAR VOLUMES

2,2′-Di­bromo-3,3′,4,4′,5,5′,6,6′-octa­m
2,2′-Di­bromo-3,3′,4,4′,5,5′,6,6′-octa­methyl-1,1′-bi­phenyl
✍ Karunadasa, Hemamala ;Leggett, Christina ;Wong, Shaun 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 190 KB

The title compound, C 29 H 24 Br 2 , has crystallographic twofold rotation symmetry. The Br atom in the 2 position is disordered with the methyl group in the 6 position. The biphenyl bridge bond distance and the torsion angle between the rings are in good agreement with similar previously reported s

{1,3-Bis(3,4,5-trimethoxy­benz­yl)-3,4,5
{1,3-Bis(3,4,5-trimethoxy­benz­yl)-3,4,5,6-tetra­hydro­pyrimidin-2-yl­idene}chloro(η4-cyclo­octa-1,5-diene)rhodium(I)
✍ Arslan, Hakan ;VanDerveer, Don ;Özdemir, İsmail ;Demir, Serpil ;Çetinkaya, Bekir 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 158 KB

In the title complex, [RhCl(C~8~H~12~)(C~24~H~32~N~2~O~6~)], the Rh atom is coordinated by a Cl atom, one C atom of the tetrahydropyrimidine ring and the two double bonds of cyclooctadiene. Each of the tetrahydropyrimidine and cyclooctadiene rings is puckered.