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Bis(quinolin-8-olato-κ2N,O)lead(II)

✍ Scribed by Zhu, Li-Hong ;Zeng, Ming-Hua ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
376 KB
Volume
61
Category
Article
ISSN
1600-5368

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(Quinolin-8-ol-κ2N,O)(quinolin-8-olato-κ
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Single-crystal X-ray study T = 299 K Mean (C-C) = 0.012 A R factor = 0.062 wR factor = 0.154 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The five-coordinate geometry of the Al atom in the title compound, [Al(C 10 H 8 NO) 2 (C 16 H 11 O)], is trigonal-bipyramidal, in which the O-donor atoms of the naphtholate and the two quinolinolate ligands are in the trigonal equatorial plane and the N atoms in the axial positions.

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The title compound, [Fe(C 9 H 6 NO) 3 ]ÁCH 3 OH, consists of a mononuclear [Fe(C 9 H 6 NO) 3 ] complex molecule and a methanol solvent molecule. The Fe III ion is coordinated by three N atoms and three O atoms from three quinolin-8-olate ligands. The six atoms around the metal form a slightly distor