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Bis(2-methyl­quinolin-8-olato-κ2N,O)(6-phenyl-2-naphtholato-κO)aluminium(III)

✍ Scribed by Rajeswaran, Manju ;Place, David W. ;Bakos, Vincent W. ;Deaton, Joseph C. ;Brown, Christopher T. ;Lenhart, William C.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
150 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The five-coordinate geometry of the Al atom in the title compound, [Al(C 10 H 8 NO) 2 (C 16 H 11 O)], is trigonal-bipyramidal, in which the O-donor atoms of the naphtholate and the two quinolinolate ligands are in the trigonal equatorial plane and the N atoms in the axial positions.

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The title compound, [Fe(C 9 H 6 NO) 3 ]ÁCH 3 OH, consists of a mononuclear [Fe(C 9 H 6 NO) 3 ] complex molecule and a methanol solvent molecule. The Fe III ion is coordinated by three N atoms and three O atoms from three quinolin-8-olate ligands. The six atoms around the metal form a slightly distor