Bis(pyridinium) tetrabromocadmate(II) monohydrate
✍ Scribed by Zhang, Hui ;Fang, Liang
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 304 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 100 K Mean (C-C) = 0.007 A Disorder in solvent or counterion R factor = 0.041 wR factor = 0.095 Data-to-parameter ratio = 29.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the crystal structure of the title compound, (C 5 H 7 N 2 ) 2 -[CoCl 4 ], the Co II ion is coordinated by four chloride ions. The Co atom lies on a crystallographic twofold rotation axis. The structure is stabilized by an extensive network of N-HÁ Á ÁCl hydrogen bonds.
In the title complex, (C 6 H 8 N) 2 [Cd(C 3 S 5 ) 2 ], the Cd II ion is coordinated by four dmit (2-thioxo-1,3-dithione-4,5-dithiolate) S atoms in a distorted tetrahedral geometry. The Nmethylpyridinium cations link with the Cd II complex anion via weak C-HÁ Á ÁS hydrogen bonding.