Bis(4-aminopyridinium) tetrathiocyanatocobaltate(II)
✍ Scribed by Shi, Jing Min ;Zhang, Feng Xia ;Lu, Jian Jun ;Liu, Lian Dong
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 236 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the crystal structure of the title compound, (C 5 H 7 N 2 ) 2 -[CoCl 4 ], the Co II ion is coordinated by four chloride ions. The Co atom lies on a crystallographic twofold rotation axis. The structure is stabilized by an extensive network of N-HÁ Á ÁCl hydrogen bonds.
In the title complex, [Cd(NCS) 2 (C 5 H 5 N) 4 ], the Cd II atom lies on a center of inversion. It is coordinated by four N atoms from four pyridines and two N atoms from two isothiocyanate ions and has a slightly distorted octahedral geometry.
Single-crystal X-ray study T = 110 K Mean '(C±C) = 0.003 A Ê R factor = 0.046 wR factor = 0.115 Data-to-parameter ratio = 19.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.