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Bisperoxovanadium compounds: synthesis and reactivity of some insulin mimetic complexes

✍ Scribed by Alan Shaver; David A. Hall; Jesse B. Ng; Anne-Marie Lebuis; Rosemary C. Hynes; Barry I. Posner


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
778 KB
Volume
229
Category
Article
ISSN
0020-1693

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✍ Anna Penner; Tobias Schröder; Thomas Braun; Burkhard Ziemer 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB

## Abstract Treatment of [Rh(μ‐Cl)(coe)~2~]~2~ (coe = cyclooctene) with 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridine (tbbpy) gives the bipyridine complex [Rh(Cl)(tbbpy)(coe)] (1). A subsequent reaction with dihydrogen results in the formation of the cluster [{Rh(Cl)(H)(tbbpy)}]~4~ (2). The reaction of [R