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Synthesis and some reactivity of pentamethylcyclopentadienyl-ruthenium complexes with an SnCl3 ligand. X-Ray crystal structure of [(C5Me5)Ru(SnCl3)(COD)]

✍ Scribed by Beatriz Moreno; Sylviane Sabo-Etienne; Françoise Dahan; Bruno Chaudret


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
539 KB
Volume
498
Category
Article
ISSN
0022-328X

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## Abstract The monoalkyl complexes [Zr{Me~2~Si(η^5^‐C~5~Me~4~)(η^5^‐C~5~H~3~R)}(R′)Cl] [R = Me, R′ = CH~2~Ph (1); R = Me, R′ = CH~2~SiMe~3~ (2); R = __i__Pr, R′ = CH~2~Ph (3); R = __i__Pr, R′ = CH~2~SiMe~3~ (4); R = SiMe~3~, R′ = CH~2~Ph (5); R = SiMe~3~, R′ = CH~2~SiMe~3~ (6)] have been synthesiz