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Oxidative addition of cationic (η6-chloroarene)tricarbonylmanganese compounds to palladium(0) complexes. Synthesis, characterisation and reactivity

✍ Scribed by Jean-François Carpentier; Yves Castanet; Jacques Brocard; André Mortreux; Françoise Rose-Munch; Claudine Susanne; Eric Rose


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
208 KB
Volume
493
Category
Article
ISSN
0022-328X

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The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h