An N 2 S 2 -donor set de®nes the approximately tetrahedral coordination environment about the zinc centre in the monomeric title compound, [Zn(S 2 CO i Pr) 2 (4,7-Me 2 phen)] or [Zn(C 4 H 7 OS 2 ) 2 (C 14 H 12 N 2 )], which has crystallographically imposed twofold rotation symmetry.
Bis(O-methyldithiocarbonato)cadmium(II)
✍ Scribed by Young Jr, Victor G. ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 230 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Co(C 2 H 3 OS 2 ) 3 ], the Co atom is coordinated by six S atoms in a distorted octahedral arrangement. The six CoÐS bond distances are in the range 2.262 (1)±2.275 (1) A Ê , with an average of 2.270 (2) A Ê .
In the title complex, [Cr(C 2 H 3 OS 2 ) 3 ], the Cr atom is coordinated by six S atoms in a distorted octahedral arrangement. The six CrÐS bond distances are in the range 2.391 (1)±2.406 (1) A Ê , with an average of 2.397 (2) A Ê .
The molecular structure of the title compound, [Zn 2 (C 4 H 7 OS 2 ) 4 (C 26 H 24 P 2 )], features two Zn(S 2 COiPr) 2 units bridged by a diphosphine ligand. The thiolate ligands are chelating but form asymmetric ZnÐS bonds, introducing considerable distortion in the coordination geometry about Zn t
Single-crystal X-ray study T = 296 K Mean '(O±C) = 0.012 A Ê R factor = 0.029 wR factor = 0.028 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.