In the title compound, [Ni(C 18 H 35 N 2 O 2 S 2 ) 2 ], the coordination geometry around the Ni atom, lying on a centre of symmetry, is square planar, consisting of four N atoms from the two vicdioxime ligands. The O atoms are intramolecularly hydrogen bonded, as is usually observed for anti-isomer
Bis(N-n-propylsalicylideneaminato)nickel(II)
β Scribed by Britton, D. ;Pignolet, L. H.
- Book ID
- 114506102
- Publisher
- International Union of Crystallography
- Year
- 1989
- Tongue
- English
- Weight
- 327 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0108-2701
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π SIMILAR VOLUMES
In the title compound, [Ni(C 6 H 19 N 4 ) 2 ][Fe(CN) 6 ], the Ni 2+ and Fe 2+ cations are both octahedrally coordinated. The complex cations and anions, both of which are centrosymmetric, are linked by a network of N-HΓ Γ ΓN hydrogen bonds to form a three-dimensional network. metal-organic papers m
In einer vor kurzem veroffentlichten Abhandlung von LUDWIG~) werden von uns ausgefuhrte rontgenographische Untersuchungen an Kristallen von Bis-(N-phenyl-acety1acetonimino)-nickel(I1) und Bis-(N-phenylsalicy1aldimino)-nickel(I1) envahnt . Die Resultate dieser jetzt abgeschlossenen Untersuchungen se