The phoochemistry of transition-metal hydride complexes has recently attracted considerable attention [l] commensurate with their importance in many transition-metal-assisted or -catalyzed organic transformations. Photoinduced elimination of molecular hydrogen seems to be a general reaction for dia
✦ LIBER ✦
Bis(diphenylphosphino)ethane complexes of iron
✍ Scribed by Ittel, S. D.; Tolman, C. A.; Krusic, P. J.; English, A. D.; Jesson, J. P.
- Book ID
- 111859292
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 975 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0020-1669
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The crystal structure of the title compound, [(dppe-P,P H )Cu-(dppeS-P)(SC{O}Ph)], [Cu(C 7 H 5 OS)(C 26 H 24 P 2 S)(C 26 H 24 P 2 )], is reported. In this monomeric compound, the Cu atom has a tetrahedral coordination geometry, with a P 3 CuS core.
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In the title compound, [Rh(C 26 H 24 ) 2 ](C 24 H 20 B), both the Rh and the B atom lie on twofold axes of symmetry. Selected geometrical parameters are Rh-P = 2.3076 (5) and 2.3114 (5) A ˚, and P-Rh-P = 82.43 (2) and 98.11 (2) .