𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis­(diethyl­enetri­amine)­mercury(II) bis­(thio­cyanate)

✍ Scribed by Tran, M. Linh ;Bernhardt, Paul V. ;Gentle, Ian R.


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
156 KB
Volume
58
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


Mercury(II) in the title compound, Hg(C 4 H 13 N 3 ) 2 2 , is six-coordinated with two diethylenetriamine (dien) ligands in a sym-facial con®guration. The complex cation has a twofold axis of symmetry, and the secondary amine groups are in trans positions.


📜 SIMILAR VOLUMES


trans-Bis(1,4-butane­di­amine)­bis­(iso­
✍ Fujimoto, Kazuya ;Nagata, Kiyonori ;Suzuki, Honoh ;Kanamori, Kan 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 223 KB

The title compound, [Co(NCS) 2 (C 4 H 12 N 2 ) 2 ]NCS, (I), has an octahedral coordination geometry, in which one of the sevenmembered chelate rings adopts the chair form and the other the twist-boat form.