Bis(diethylenetriamine)nickel(II) tetracyanonickelate(II)
✍ Scribed by Muga, Iñaki ;Vitoria, Pablo ;Reinoso, Santiago ;Gutiérrez-Zorrilla, Juan M.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 330 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Mercury(II) in the title compound, [Hg(C 4 H 13 N 3 ) 2 ](SCN) 2 , is six-coordinated with two diethylenetriamine (dien) ligands in a sym-facial con®guration. The complex cation has a twofold axis of symmetry, and the secondary amine groups are in trans positions.
The asymmetric unit of the title compound, [Ni(C 4 H 13 N 3 )-(C 6 H 8 N 3 O 2 )]IÁH 2 O, comprises a six-coordinated Ni(II) complex cation, an I À anion, and one water molecule of crystallization. Intermolecular hydrogen bonds link the complex cations into extended two-dimensional layers.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.045 wR factor = 0.125 Data-to-parameter ratio = 23.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.