Bis(aqua)bis(benzimidazole-κN)bis(5-fluorouracil-1-acetate-κO)cobalt(II)
✍ Scribed by Hu, Mao-Lin ;Zhu, Nan-Wen ;Xiao, Hong-Ping
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 366 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 295 K Mean (C-C) = 0.004 A R factor = 0.043 wR factor = 0.105 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Cu(Cl~2~CHCO~2~)~2~(C~6~H~6~N~2~O)~2~(H~2~O)], both the Cu^II^ atom and the O atom of the coordinated water molecule lie on a crystallographic twofold rotation axis. The Cu^II^ atom is coordinated by O atoms from two monodentate chloroacetate anions, pyridine N atoms from two
In the title compound, [Cd(C 7 H 5 O 3 ) 2 (C 7 H 6 N 2 ) 2 ]ÁH 2 O, the Cd II ion is surrounded by two salicylate anions and two benzimidazole molecules in a strongly distorted octahedral cis-CdN 2 O 4 geometry. The partially overlapped arrangement and the face-to-face distances of 3.22 (3) and 3.3