Bis(9-hydroxyfluorene-9-carboxylato-κ2O,O′)bis(3-hydroxypyridine-κN)copper(II) methanol disolvate
✍ Scribed by Gao, Shan ;Huo, Li-Hua ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 195 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Copper diacetate monohydrate (0.20 g, 1 mmol) was dissolved in methanol (20 ml) and 9-hydroxyfluorene-9-carboxylic acid (0.44 g,
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê Disorder in solvent or counterion R factor = 0.034 wR factor = 0.086 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, {[Cu(C 7 H 4 O 4 ) 2 ]Á2CH 3 OH} n , forms a square-planar complex through two N,O-chelating pyridine-2,3-dicarboxylate ligands. Axial interactions between Cu II and O atoms of the CO 2 H groups in the meta-positions of adjacent ligands form one-dimensional chains. Incorporation
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.005 A Ê R factor = 0.039 wR factor = 0.141 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.