𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis(4-phenylpyridinium) tetrakis(nitrato-κ2O,O′)stannate(IV)

✍ Scribed by Zhong, H. ;Zeng, X.-R. ;Yang, X.-M. ;Luo, Q.-Y.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
630 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The asymmetric unit of the title compound, (C 11 H 9 N) 2 -[Sn(NO 3 ) 4 ], consists of a mononuclear complex anion and two non-coordinated 4-phenylpyridinium cations. The Sn IV atom, lying on a twofold rotation axis, is coordinated by eight O atoms of four NO 3 À anions. This mononuclear complex is further extended into a supramolecular network structure via non-classical hydrogen bonds between CH groups of cations and O atoms of neighbouring anions.

📜 SIMILAR VOLUMES

Bis(malonamide-κ2O,O′)bis­(nitrato-κO)co
Bis(malonamide-κ2O,O′)bis­(nitrato-κO)copper(II)
✍ Ershov, Mikhail A. ;Skvortsov, Vikenty G. ;Pilchikova, Yulia Yu. ;Koltsova, Olga 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 251 KB

The title complex, [Cu(NO 3 ) 2 (C 3 H 6 N 2 O 2 ) 2 ], exists in the crystal structure as a monomer and possesses a crystallographically imposed center of symmetry. The Cu atom is coordinated by six O atoms [Cu-O = 1.9339 (10)-2.3964 (11) A ˚] from two chelating malonamide ligands and two terminal

Diaqua­tris(nitrato-κ2O,O′)bis­(4-pyrido
Diaqua­tris(nitrato-κ2O,O′)bis­(4-pyridone-κO)lanthanum(III)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 315 KB

In the mononuclear title compound, [La(NO 3 ) 3 (C 5 H 5 NO) 2 -(H 2 O) 2 ], the La III atom is ten-coordinate, with a coordination polyhedron made up of the O atoms of two 4-pyridone ligands, six O atoms of three O,O 0 -chelating nitrate groups and two water molecules, the polyhedron approximating

Aqua(nitrato-κ2O,O′)bis(4-nitrobenzohydr
Aqua(nitrato-κ2O,O′)bis(4-nitrobenzohydrazide-κ2N2,O)cadmium(II) nitrate
✍ Chundak, S. Yu. ;Lukachinec, L. Yu. ;Daszkiewicz, M. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 470 KB

In the title compound, [Cd(NO~3~)(C~7~H~7~N~3~O~3~)~2~(H~2~O)]NO~3~, the Cd atom is coordinated by two organic ligands, a water molecule and a nitrate anion. The coordination can be described as distorted pentagonal bipyramidal. Geometric parameters show that the nitrate anion is coordinated in the