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Aqua(nitrato-κ2O,O′)bis(4-nitrobenzohydrazide-κ2N2,O)cadmium(II) nitrate

✍ Scribed by Chundak, S. Yu. ;Lukachinec, L. Yu. ;Daszkiewicz, M.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
470 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Cd(NO~3~)(C~7~H~7~N~3~O~3~)~2~(H~2~O)]NO~3~, the Cd atom is coordinated by two organic ligands, a water molecule and a nitrate anion. The coordination can be described as distorted pentagonal bipyramidal. Geometric parameters show that the nitrate anion is coordinated in the bidentate mode. Non-coordinated and bidentate chelating nitrates create hydrogen-bonding networks in the a- and b-axis directions, respectively. Parallel-oriented 4-nitrobenzohydrazides help to establish the packing.


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