In the title complex, [Cu(C~8~H~5~O~3~)(NO~3~)(C~12~H~8~N~2~)(H~2~O)], the Cu^II^ atom adopts a distorted square-pyramidal coordination geometry with an O atom of the nitrate group occupying the apex of the pyramid. The complex molecules are linked into ribbons along the __a__ axis __via__ hydrogen
Aquatetrakis(2-methylpyrazine-κN)(nitrato-κO)copper(II) nitrate
✍ Scribed by Otieno, Tom ;Pinkston, Andrea T. ;Johnson, Natisha C. ;Parkin, Sean
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 274 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 173 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.049 wR factor = 0.129 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In the title compound, [Cd(NO~3~)(C~7~H~7~N~3~O~3~)~2~(H~2~O)]NO~3~, the Cd atom is coordinated by two organic ligands, a water molecule and a nitrate anion. The coordination can be described as distorted pentagonal bipyramidal. Geometric parameters show that the nitrate anion is coordinated in the
The title compound, [Cu(CH~3~CO~2~)~2~(C~9~H~7~N~3~O)~2~(H~2~O)], is a mononuclear complex in which the Cu^II^ atom assumes a square-pyramidal coordination geometry. The Cu atom and the aqua O atom lie on a crystallographic twofold rotation axis. In the crystal structure, there are hydrogen bonds an
The structure of (I), showing 30% probability displacement ellipsoids and the atom-numbering scheme.