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Bis(4-methoxybenzaldehyde 2-hydroxybenzoylhydrazonato)pyridinezinc(II) pyridine solvate

✍ Scribed by Tai, Xi-Shi ;Yin, Jie ;Hao, Ming-Yang


Book ID
104491261
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
786 KB
Volume
63
Category
Article
ISSN
1600-5368

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Reaction of 2,4-dihydroxybenzaldehye salicylhydrazide (L) with Zn(OAc) 2 Á2H 2 O in a mixed solvent of pyridine and N,Ndimethylformamide (DMF) resulted in the formation of the title complex, [Zn 2 (C 14 H 10 N 2 O 4 ) 2 (C 5 H 5 N) 2 ]Á2C 3 H 7 NO. The asymmetric unit contains one complete neutral z

[1-(5-Chloro-2-oxido­phenyl)­ethanone 4-
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The double chelate ring in the title complex, [Ni(C 15 H 11 Cl-N 3 O 3 ) 2 ]ÁC 5 H 5 N, is essentially planar, with the O,N,O-donor atoms and a pyridine ligand N atom occuping the equatorial positions in a distorted octahedral environment about the Ni atom. The NÐNiÐN axial bond angle is 173.16 (8)