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Bis(3-tert-butyl-N,5-di­methyl­salicyl­aldiminato)­cobalt(II)

✍ Scribed by Li, Xiaoyan ;Huang, Liye ;Dong, Shuli ;Li, Mu ;Sun, Hongjian

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
190 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Co(C 13 H 18 NO) 2 ], was synthesized by the disproportionation of methyl-tetrakis(trimethylphosphine)cobalt with 3-tert-butyl-N,5-dimethylsalicylaldimine in diethyl ether. The cobalt center in the structure is in a distorted tetrahedral geometry.

📜 SIMILAR VOLUMES

{[μ-Bis­(salicyl­idene)-1,3-propane­diam
{[μ-Bis­(salicyl­idene)-1,3-propane­diaminato]bis(3,5-di­methyl­pyridine)nickel(II)}di­bromo­zinc(II)
✍ Ülkü, Dinçer ;Kaynak, F. Betül ;Atakol, Orhan 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 352 KB

The title compound, [NiZnBr 2 (C 17 H 16 N 2 O 2 )(C 7 H 9 N) 2 ], is a double oxygen-bridged heterometal complex based on a Schiff base ligand. The Ni atom has an irregular octahedral environment involving two bridging O and two N atoms from a SALPD 2À [N,N H -bis(salicylidene)-1,3-propanediaminate

{N,N′-Bis­[3-methoxy­methyl-5-methyl­sal
{N,N′-Bis­[3-methoxy­methyl-5-methyl­salicyl­idene]-(R,R)-1,2-di­phenyl­enedi­amino}nickel(II)
✍ Wu, Jin-Cai ;Tang, Ning ;Yu, Kai-Bei 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 459 KB

Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.006 A Ê R factor = 0.043 wR factor = 0.100 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.