The dihedral angle between the benzene rings in the title compound, C 12 H 7 Cl 3 , is 47.25 (4) .
Bis(2,4,6-trichlorophenyl) 2-ethylmalonate
✍ Scribed by Wentrup, Curt ;Buchanan, Jeff ;Byriel, Karl A. ;Kennard, Colin H. L.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 481 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.034 wR factor = 0.103 Data-to-parameter ratio = 13.7
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The structure of the title compound, C 6 H 21 N 4 3+ Á3C 14 H 10 -Cl 2 NO 2 À Á6H 2 O, comprises the 1:3 organic salt of tris(2ethylamine)amine and diclofenac acid, with an approximated six water molecules in an extensive hydrogen-bonding network. Two water molecules exist as full-occupancy molecule
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.002 A Ê R factor = 0.050 wR factor = 0.115 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~14~H~17~ClN~2~O~3~, adopts a keto–hydrazo tautomeric form stabilized by an intramolecular N—H...O hydrogen bond. The molecule is roughly planar.
The title compound, C 32 H 23 Cl 2 N, was synthesized via the Ullmann reaction. The orientations of the three aromatic rings attached to the vinyl group are determined by the sp 2 state of the vinyl C atoms. The crystal packing is stabilized by weak CÐHÁ Á Á% interactions.
The title compound, C 25 H 26 O 2 , was isolated and characterized as a stable intermediate in the conversion of 2,2-diphenylethyl 2,4,6-trimethylphenyl ketone to its formaldehyde-derived enone.