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Bis[2,4-dibromo-6-(1-naphthyliminomethyl)phenolato-κ2N,O]bis(N,N′-dimethylformamide-κO)cobalt(II)

✍ Scribed by Liu, Zheng ;Jin, Li Xia ;Xia, Jin Hong ;Liu, Er Xi ;Li, Guang Zhao


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
835 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Co(C 17 H 10 Br 2 NO) 2 (C 3 H 7 NO) 2 ], the cobalt(II) cation is coordinated by two N and two O atoms from two different Schiff base ligands, and two O atoms from dimethylformamide molecules, forming a slightly distorted octahedral geometry. In the crystal structure, C-HÁ Á ÁBr hydrogen bonds link the molecules in rows.

Related literature

Schiff bases of isatin have been reported to possess antibacterial, antifungal, antiviral, anti-HIV, antiprotozoal and anthelmintic activities (Erc ¸ag ˘et al., 2006).


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Bis[2-(1-naphthyliminomethyl)phenolato-κ
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In the title complex, [Cu(C 17 H 12 NO) 2 ], the Cu II ion is coordinated by two bidentate ligands in a trans arrangement, forming a CuN 2 O 2 slightly distorted square-planar configuration.

Bis[2-(2-naphthyliminomethyl)phenolato-κ
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In the title complex, [Zn(C 17 H 12 NO) 2 ], the Zn II ion is coordinated by two N,O-bidentate ligand molecules in a distorted tetrahedral geometry. The crystal packing may be stabilized by weak C-HÁ Á ÁCg interactions [Cg is a ring centroid; HÁ Á ÁCg = 2.95 A ˚].