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Bis(2,2′:6′,2′′-terpyridyl-κ3N)­manganese(II) dinitrate dihydrate

✍ Scribed by Rompel, Annette ;Bond, Andrew D. ;McKenzie, Christine J.


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
296 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the crystal structure of the title compound, [Mn(C 15 H 11 -N 3 ) 2 ](NO 3 ) 2 Á2H 2 O, at 180 K, the complex cation lies on a twofold axis.


📜 SIMILAR VOLUMES


Bis[4′-(4-methylphenyl)-2,2′:6′,2′′-terp
✍ Liu, Han-Guo ;Qiu, Yong-Cai ;Wu, Jian-Zhong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 667 KB

In the title complex, [Mn(C 22 H 17 N 3 ) 2 ](ClO 4 ) 2 , the MnN 6 coordination geometry is distorted octahedral, involving the six N atoms of two 4 0 -(4-methylphenyl)-2,2 0 :6 0 ,2 00 -terpyridine (ttp) ligands. The two chelated ttp planes are almost perpendicular, with a dihedral angle of 89.1 (