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Bis(2-amino­pyridine)(2,2′-bi­pyridine)­platinum(II) tetra­cyano­platinate(II) dihydrate

✍ Scribed by Sakai, Ken ;Mizota, Mina ;Akiyama, Norinobu

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
417 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Pt(C 10 H 8 N 2 )(C 5 H 6 N 2 ) 2 ][Pt(CN) 4 ]Á-2H 2 O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the %±% stacking associations between the 2,2 H -bipyridine moieties, contribute to the stabilization of the crystal packing. Two different PtÁ Á ÁPt distances [5.2034 (6) and 4.5599 (6) A Ê ] alternate along the one-dimensional stack.

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