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Bis(4,4′-bi­pyridine)­tetra­aqua­cobalt(II) 2,6-naphathalenedi­carboxyl­ate dihydrate

✍ Scribed by Almeida Paz, Filipe A. ;Khimyak, Yaroslav Z. ;Klinowski, Jacek

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
429 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.005 A Ê R factor = 0.046 wR factor = 0.121 Data-to-parameter ratio = 11.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.114 Data-to-parameter ratio = 9.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The Cu^II^ ion of the title complex, [Cu(SO~4~)(C~15~H~11~N~3~O)(H~2~O)]·2H~2~O, exhibits a square-pyramidal coordination geometry, defined by the three N-atom donors of a 2,6-bis(pyridin-2-yl)pyridin-4-ol ligand and an O atom of a sulfate group in the basal plane, and by an aqua ligand in the apica