In the title compound, [Co(C 11 H 9 ClN 3 O 2 ) 2 ]Á2.5H 2 O, the Co II atom, which lies on a twofold rotation axis, is coordinated by four N atoms and two O atoms from two ligands in a distorted octahedral geometry. In the crystal structure, molecules are linked together by intermolecular O-HÁ Á ÁO
Bis{2′-[(5-chloro-1H-3-indolyl)methylene]-2-(1H-3-indolyl)acetohydrazido-κ2N,O}nickel(II) dimethyl sulfoxide disolvate
✍ Scribed by Ali, Hapipah M. ;Nazzatush, S. Jamaludin ;Rizal, Mohd. Razali ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 435 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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In the title compound, [Zn(C 13 H 9 N 2 O) 2 ]Á2C 3 H 7 NO, the Zn II ion is located on a twofold axis and chelated by two 2-(2hydroxyphenyl)benzimidazole ligands with a distorted tetrahedral geometry.
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.004 A Ê R factor = 0.041 wR factor = 0.094 Data-to-parameter ratio = 20.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Ni(C 17 H 14 N 3 O 2 ) 2 ]Á2C 3 H 7 NOÁ2H 2 O, contains Ni II cations (site symmetry 1) chelated by two deprotonated Schiff bases in a trans-NiN 2 O 2 square-planar geometry. The complex molecule and the dimethylformamide (DMF) and water molecules interact by way of O-HÁ Á ÁO an